Macromolecules - AP Biology

A fat is a lipid with three fatty chains linked by an ester linkage to glycerol.

A fatty acid consists of a hydrocarbon chain (carbons bound to hydrogen), with even numbers of carbons from 4 to 28, and a carboxyl group at one end. A triglyceride consists of three fatty acids with their carboxyl end bound to glycerol via an ester bond.

A phospholipid has two fatty acid tails, which consist of hydrocarbons with even numbers of carbons ranging from 4 to 28, and a phosphate group attached to a glycerol head, which is hydrophilic. Monoglycerides contain only one fatty acid chain bound to a glycerol head, and triglycerides contain three fatty acid chains.

Monosaccharides such as fructose are carbohydrates not lipids. Waxes, steroid hormones such as testosterone, estrogen and progesterone, and triglycerides (fats) are composed mainly of hydrocarbons and are classified as lipids.

Glycogen is a carbohydrate. It is a polysaccharide that animals use to store glucose when sugars are needed by the body for fuel. All other answer choices are lipids.

Chitin is a carbohydrate. Specifically, it is a polysaccharide used by arthopods to build exoskeletons, and is found in the cell walls of fungi. Waxes are types of lipids, and nucleic acids are DNA and RNA.

The formation of disulfide bridge occurs in the tertiary and/or quaternary level of protein structure. This involves two sulfur atoms sharing a lone pair of electrons to form a covalent bond, which enhances the integrity of the protein's structure. The amino acid that is involved in forming disulfide bridges is cysteine.

Monosaccharides are the smallest unit of carbohydrates. A disaccharide is made up of two monosaccharides joined together. A string of monosaccharides linked together is a polysaccharide.

Chitin is a structural polysaccharide used by arthropods to build their exoskeletons. Chitin is also found in fungi as well. Cellulose is the structural component found in the cell walls of plants.

Arthropods use the polysaccharide chitin to build their exoskeletons. Certain types of fungi also use chitin instead of cellulose for building their cell walls.

Chitin is a type of polysaccharide that is present in the exoskeletons of arthropods, and is the primary substance of the cell wall of fungi. In general, polysaccharides are chains of simple sugars. Another example of a polysaccharide is starch. Waxes are types of lipids. Hemoglobin is a protein, which is made of amino acids. DNA is a nucleic acid, which is a polymer of nucleotides.

A saturated fat contains no double bonds in its fatty acid chain. Just remember that saturated means the fat is saturated with hydrogens. Double bonds eliminate two hydrogen atoms per occurrence, and are present in unsaturated fats.

Enzymes are not changed or consumed by the reactions they catalyze, but can be altered by environmental conditions. They work in three-dimensional active sites to bind specific substrates and lower the activation of certain reactions, subsequently increasing the reaction rate. Reaction rate can be further increased when enzymes react with cofactors or coenzymes, but decreased when enzymes are blocked from their specified active sites by competitive inhibitors.

Fats have an incredibly high potential to produce a lot of energy when broken down. This is because they are very saturated, which means they have a lot of bonded hydrogens. They also have a lot of carbon-carbon bonds, which have a lot of potential energy stored. When you break down a fat, especially one that has fourteen or more carbons in the chain, you release the energy from every carbon-carbon and carbon-hydrogen bond.

Comparing this to a sugar, alcohol, or protein (amino acids make up proteins), we can see that there aren't as many of these bonds to break. Proteins, in fact, require a lot of energy to break down because they have to be converted into other forms first.

Amphipathic molecules have both a polar and nonpolar region. This amphipathic quality allows phospholipids to create the plasma membrane in eukaryotic cells. The polar region is the phosphate head, which interacts with the aqueous cytosol and extracellular environment. The nonpolar region is the fatty acid tail, which is sequestered in the bilayer of the membrane and helps reduce the permeability to certain molecules.

Macromolecules, such as proteins, nucleic acids, and polysaccharides, are composed of monomers. Each polymer is made from at least two smaller monomers. Protein monomers are amino acids, nucleic acid monomers are nucleotides, and polysaccharide monomers are monosaccharides. In order to form polymers, the monomers must form covalent bonds with one another.

For proteins, these covalent bonds are peptide bonds, and for saccharides they are glycosidic linkages.

Nucleotides are the monomers that make up nucleic acids. They are composed of a five-carbon sugar, a nitrogenous base, and a phosphate group. In building the polymer nucleic acid chain, the sugar and phosphate of one nucleotide align with those of another to build the phosphate-sugar backbone, while the nitrogenous bases will form hydrogen bonds across the helix to link two chains of nucleotides together. Phosphate groups carry negative charge; this gives the cell nucleus an overall negative charge and can be used to generate electrochemical gradients across the nuclear membrane.

Carboxylic acids are found in amino acids, and are not present in nucleic acids.

Water is a very polar substance that will not interact well with nonpolar macromolecules. Enzymes (proteins), oligosaccharides (carbohydrates), and nucleic acids all contain polar regions that make them soluble in aqueous environments. Lipids, however, are hydrocarbons and generally lack a polar region. Lipids would not be soluble in water, but would be soluble in nonpolar organic solvents, like chloroform. We can conclude that cholesterol is a lipid.

Chargaff found that in double-stranded DNA, the number of guanine bases should be equal to the number of cytosine bases, and the number of adenine bases should equal the number of thymine bases. These rules proved to be important pieces of evidence for the idea of complementarity, the theory that each DNA base pairs only with a specific other base on its opposite strand.

According to Chargaff's rules, the statement regarding guanine and cytosine bases is correct. The two other statements that are similarly worded are not correct because they do not compare the frequencies of two bases that are complementary to each other (adenine will not bind cytosine and guanine will not bind thymine). Finally, guanine-cytosine bonds are more stable than adenine-thymine bonds.