Molecular Structure of Acids and Bases

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AP Chemistry › Molecular Structure of Acids and Bases

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1

Put the following acids in order of their INCREASING acid strength: HI, HCl, HBr, HF.

HI, HCl, HBr, HF

0

HF, HCl, HBr, HI

CORRECT

HI, HBr, HCl, HF

0

HF, HBR, HI, HCl

0

HCl, HBr, HI, HF

0

Explanation

Larger halogen size leads to greater acidity because of weaker H-X interactions.

2

Put the following in order of INCREASING acid strength: H2Se, KH, AsH3, HBr.

KH, AsH3, H2Se, HBr

CORRECT

HBr, H2Se, AsH3, KH

0

AsH3, H2Se, HBr, KH

0

AsH3, H2Se, KH, HBr

0

KH, H2Se, AsH3, HBr

0

Explanation

Acid strength increases going across a period.

3

Put the following acids in order of their INCREASING acid strength: HCl, HS, HBr, H2Se.

HCl, HS, HBr, H2Se

0

H2Se, HBr, HS, HCl

0

HBr, H2Se, HCl, H2S

0

H2S, HCl, HBr, H2Se

0

H2S, H2Se, HCl, HBr

CORRECT

Explanation

Acid strength increases from left to right across a period and increases going down a group.

4

Put the following acids in order of their DECREASING acid strength: HOCl, HOBr, HOI, H2O.

HOCl, HOBr, HOI, H2O

CORRECT

H2O, HOI, HOBr, HOCl

0

HOI, HOBr, HOCl, H2O

0

H2O, HOCl, HOBr, HOI

0

HOCl, H2O, HOBr, HOI

0

Explanation

Acid strength of an oxy acid increases with increasing electronegativity on the halogen.

5

Put the following acids in order of their DECREASING acid strength: HOCl, HO2Cl, HO3Cl, HO4Cl.

HOCL, HO2Cl, HO3Cl, HO4Cl

CORRECT

HOCl, HO4Cl, HO2Cl, HO3Cl

0

HO4Cl, HO3Cl, HO2Cl, HOCl

0

HO4Cl, HOCl, HO2Cl, HO3Cl

0

HO2Cl, HOCl, HO3Cl, HO4Cl

0

Explanation

For an oxyacid, the acid strength increases as the number of oxygens increase.