Spectroscopy and Electromagnetic Spectrum

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AP Chemistry › Spectroscopy and Electromagnetic Spectrum

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1

What photon wavelength can promote a transition from the n = 1 (ground state) to the n = 3 (excited state)?

204 nm

0

306 nm

0

102 nm

CORRECT

408 nm

0

1 m

0

Explanation

;

2

What is the energy of a photon that has a wavelength of 540 nm?

CORRECT

0

0

0

None of the above

0

Explanation

; ;

3

A student has a Blue #1 dye with a molar absorptivity of 1.30 x 105 M-1 cm-1 at 631 nm. If the student runs this sample through a spectrophotometer and finds it has an absorption of 0.500 what is the dye’s molarity? Assume a path length of 1.0 cm.

0

0

0

0

CORRECT

Explanation

;

4

A 3.0 eV light is shined on Gold ( Փ = 5.1 eV), silver (Փ =4.26 eV), Cesium (Փ = 2.1 eV), and Platinum (Փ = 6.35). If Փ is the work function of the metal, what metal would have electrons ejected?

Au

0

Ag

0

Cs

CORRECT

Pt

0

Au, Ag, and Pt

0

Explanation

The work function is the energy required to remove an electron from a metal. Only Cs metal has a work function less than the energy of the light.

5

What transition would emit the longest wavelength of light?

n = 4 to n = 1

0

n = 3 to n = 1

0

n = 2 to n = 1

0

n = 4 to n = 3

CORRECT

Not enough information given

0

Explanation

Wavelength is inversely proportional to energy. Since the transition from n=4 to n=3 is the lowest energy transition, it would have the longest wavelength.