Oxidation Number - MCAT Chemical and Physical Foundations of Biological Systems

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Question

What is the oxidation number of chromium in calcium dichromate (CaCr2O7)?

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Answer

Since the calcium ion has a charge of +2, the dichromate anion must have a charge of -2. Oxygen always has an oxidation number of -2, so the seven oxygens in the molecule have a total number of -14. That leaves a charge of +12 that the two chromiums must balance out (-2 - (-14) = 12). Each chromium must therefore have an oxidation number of +6.

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