Atoms, Elements, and the Periodic Table - MCAT Chemical and Physical Foundations of Biological Systems

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Question

Which of the following elements has the greatest effective nuclear charge?

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Answer

The effective nuclear charge is the attractive charge a valence electron feels from the nucleus. As you move from left to right along a period, and more positive charges (protons) fill up the nucleus, the more attraction the valence electron feels. As you move down a group, you jump into the next electron shell, thus shielding the valence electrons from the inner positive charge, and decreasing the effective nuclear charge.

Because chlorine is in the same period as phosphorus and sodium, but has the most protons in its shell (the most right within the same period) it has the greatest effective nuclear charge. Additionally, because chlorine is in the same group as bromine, but is higher up on the periodic table, it has a greater effective nuclear charge, making it the correct answer.

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